首页> 外国专利> A method for the production of fluorochlorohydrocarbon - free polyurethane - flexible foams with the use of a polyisocyanate mixture containing urethane groups on diphenylmethane - diisocyanate base as well as such modified polyisocyanate mixtures

A method for the production of fluorochlorohydrocarbon - free polyurethane - flexible foams with the use of a polyisocyanate mixture containing urethane groups on diphenylmethane - diisocyanate base as well as such modified polyisocyanate mixtures

机译:一种使用在二苯基甲烷-二异氰酸酯基上包含氨基甲酸酯基团的多异氰酸酯混合物以及这种改性的多异氰酸酯混合物来生产无氟氯烃的聚氨酯-软质泡沫的方法

摘要

items of the invention are a process for the production of cfc free polyurethane soft foams (form) through implementation of $(a) liquid, urethangruppen containing bound polyisocyanatmischungen containing nco groups of 20 to 30% by weight.-%the part produced by implementing a mixture of diphenylmethan - diisocyanaten and polyphenyl - polymethylen - polyisocyanaten (crude mdi) with a polyether polyolmischung with a hydroxylzahl 120 to 25 from at least one polyoxypropylene glycol and at least one trifunkti onellen polyoxypropylene polyoxyethylene polyol containing ethylenoxideinheiten from 90 to 10wt.-% or by application of 4,4 '- diphenylmethan - diisocyanates (mdi) or mdi isomer mixture with said polyetherpolyolmischung to nco groups containing quasipru00e4polymeren and dilution of this quasipru00e4polymeren with crude mdi,with $a (b) hu00f6hermolekularen polyhydroxylverbindungen and, where appropriate, $a (c) low molecular weight kettenverlu00e4ngerungs and / or vernetzungsmitteln $a $a (d) in the presence of propellant, $a (e) catalysts and, where appropriate, $a (f) tools and / or additives, $a and erfindungsgemu00e4u00df type products with urethangruppen modified polyisocyanatmischungen (a).
机译:本发明的项目是通过实施$(a)液体,含有结合的聚异氰酸酯次春基的,含有20至30重量%的nco基团的尿道豆素的液体来生产无cfc的聚氨酯软泡沫(形式)的方法。二苯基甲烷-二异氰酸酯和聚苯基-多亚甲基-多异氰酸酯(粗制的mdi)与聚醚多元醇的混合物,该聚醚多元醇与至少一种聚氧丙二醇和至少一种含有90至10wt .-%的乙氧基亚乙基天冬氨酸的三级芳基聚氧丙烯聚氧乙烯多元醇的羟基苯酚为120至25。或通过将4,4'-二苯基甲烷-二异氰酸酯(mdi)或mdi异构体混合物与所述聚醚多醇密混合物应用于含有准四元共聚物的nco基团并用粗mdi稀释该准四元共聚物,并与$ a(b)h和$ a(c)低分子量kettenverl和/或vernetzungsmittel n $ a $ a(d)存在推进剂,$ a(e)催化剂以及适当情况下的$ a(f)工具和/或添加剂,$ a和经尿烷改性的erfindungsgem u00e4 u00df型产品多异氰酸根(a)。

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