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METHOD FOR SYNTHESIZING C60 WITH PLASMA

机译:等离子体合成C60的方法

摘要

PURPOSE:To synthesize C60 at a lowered production cost by using a specific atmospheric pressure discharge device, adding a carbon raw material gas to a rare gas in a discharged state, producing the C60 with the energy of the discharged state, and subsequently depositing the produced C60 on a substrate. CONSTITUTION:An Ar/He rare gas mixture is charged at a prescribed flow rate into an atmospheric pressure discharge device in which a cylindrical dielectric substance such as quartz glass is placed between a central electrode such as a W electrode and an outside electrode such as a stainless steel electrode, both being placed in a coaxially cylindrical shape. A high frequency electric power is applied to the flow of the gas from a high frequency electric source to produce the rare gas of a stable plasma discharge state having a temperature of =1000 K. A carbon raw material such as vaporized naphthalene is charged together with a carrier gas such as Ar into a discharge space at the tip of the central electrode and kept for a prescribed time. A substrate such as a borosilicate glass plate is placed at the tip of the cylindrical dielectric substance to deposit the product on the substrate. After the finish of the reaction, the resultant product is extracted with hexane, etc., to provide the C60.
机译:目的:通过使用特定的大气压排放装置以较低的生产成本合成C60,将碳原料气体添加到处于排放状态的稀有气体中,以排放状态的能量生产C60,然后将生成的碳沉积C60在基材上。组成:将Ar / He稀有气体混合物以规定的流量装入大气压放电装置,在该装置中,将圆柱形石英玻璃等介电质置于W电极等中心电极与H电极等外部电极之间。不锈钢电极,均以同轴圆柱形状放置。向来自高频电源的气体流施加高频电力,以产生温度<= 1000 K的稳定的等离子体放电状态的稀有气体。将诸如汽化萘的碳原料一起装入用氩气等载气进入中心电极尖端的放电空间,并保持规定的时间。将诸如硼硅酸盐玻璃板之类的基板放置在圆柱形介电物质的尖端以将产物沉积在基板上。反应完成后,将所得产物用己烷等萃取,以提供C 60。

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