首页> 外国专利> RECOVERY OF NOBLE METALS FROM INORGANIC AND/OR ORGANIC RESIDUE BY CONTACTING THE RESIDUE WITH TELLURIUM OR A REDUCIBLE TELLURIUM COMPOUND CHARACTERISED BY ADDING HIGH BOILING SOLVENT BEFORE FURTHER TREATMENT

RECOVERY OF NOBLE METALS FROM INORGANIC AND/OR ORGANIC RESIDUE BY CONTACTING THE RESIDUE WITH TELLURIUM OR A REDUCIBLE TELLURIUM COMPOUND CHARACTERISED BY ADDING HIGH BOILING SOLVENT BEFORE FURTHER TREATMENT

机译:通过用碲或可还原的碲化合物(通过进一步处理前添加高沸点溶剂)处理的污染物从无机和/或有机残留物中回收贵金属

摘要

The present invention concerns a process for the recovery of a noble metal from an inorganic and/or organic residue in the form of a tellurium amalgam characterised by adding a solvent having a boiling point above 120 DEG C to the residue, removing by distillation water and other residual solvents having boiling points below the boiling point of the added solvent, adding the tellurium or reducible tellurium compound, and then refluxing at atmospheric pressure before separating the amalgam of the noble metal. The process of the present invention also allows the simultaneous recovery of the tertiary phosphine as its oxide from a residue containing a tertiary phosphine by the further stages of concentrating the mother-liquors remaining after separation of the amalgam of the noble metal, recovering the added high boiling point solvent and isolating the tertiary phosphine in the form of its oxide by precipitation with water.
机译:本发明涉及一种从碲化汞合金形式的无机和/或有机残余物中回收贵金属的方法,其特征在于,向残余物中加入沸点高于120℃的溶剂,用蒸馏水除去。沸点低于添加的溶剂的沸点的其他残留溶剂,添加碲或可还原的碲化合物,然后在大气压下回流,然后分离出贵金属的汞齐。本发明的方法还允许通过进一步步骤浓缩从贵金属的汞齐分离后剩余的母液,回收添加的高价碘,同时从包含叔膦的残余物中回收叔膦作为其氧化物。沸点溶剂,并通过用水沉淀分离其氧化物形式的叔膦。

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