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Production of ceramic materials by pyrolysis of highly crosslinked polymeric carbodiimides

机译:通过高度交联的聚合物碳二亚胺热解制备陶瓷材料

摘要

The invention concerns a process for producing ceramic materials by pyrolysis of a polymer ceramic precursor. The ceramic precursor is produced by (a) reacting halides of elements selected from groups IIIA, IVA and VA of the periodic system, transition metals and rare-earth elements with a compound of the formula (I): R3 Si-N=C=N-SiR3, in which R, independently in each case, means a C1-C3 alkyl or alkenyl group, and (b) separating volatile components from the reaction mixture.
机译:本发明涉及通过热解聚合物陶瓷前体生产陶瓷材料的方法。陶瓷前体是通过以下方法生产的:(a)使选自元素周期表的IIIA,IVA和VA组的元素的卤化物,过渡金属和稀土元素与式(I)的化合物反应: N-SiR 3,其中R在每种情况下分别独立地是指C 1 -C 3烷基或烯基,和(b)从反应混合物中分离挥发性组分。

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