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Production of ceramic materials by pyrolysis of highly crosslinked polymeric carbodiimides as ceramic precursor as well as ceramic precursor

机译:通过热解高度交联的聚合物碳二亚胺作为陶瓷前体以及陶瓷前体来生产陶瓷材料

摘要

The invention concerns a process for producing ceramic materials by pyrolysis of a polymer ceramic precursor. The ceramic precursor is produced by (a) reacting halides of elements selected from groups IIIA, IVA and VA of the periodic system, transition metals and rare-earth elements with a compound of the formula (I): R3 Si-N=C=N-SiR3, in which R, independently in each case, means a C1-C3 alkyl or alkenyl group, and (b) separating volatile components from the reaction mixture.
机译:本发明涉及通过热解聚合物陶瓷前体生产陶瓷材料的方法。陶瓷前体是通过以下方法生产的:(a)使选自元素周期表的IIIA,IVA和VA组的元素的卤化物,过渡金属和稀土元素与式(I)的化合物反应: N-SiR 3,其中R在每种情况下分别独立地是指C 1 -C 3烷基或烯基,和(b)从反应混合物中分离挥发性组分。

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