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Fe-Ni-based austenitic alloy excellent in irradiation resistance and sodium corrosion resistance and method of setting alloy components

机译:耐辐射性和耐钠腐蚀性优异的Fe-Ni基奥氏体合金以及合金成分的凝固方法

摘要

PURPOSE:To obtain an Fe-Ni base austenitic alloy excellent in neutron irradia tion resistance by specifying the compsn. constituted of C, Si, Mn, Cr, Ni, Mo, W and Fe. CONSTITUTION:This Fe-Ni base austenitic alloy is the one constituted of, by weight, =0.2% C, =0.5% Si, =1.0% Mn, 13 to 18% Cr, 30 to 50% Ni, 2.0 to 6.0% Mo+W as well as 0.4 to 0.6 Mo/(Mo+W), if required, furthermore mixed with 0.10 to 0.30% Nb and =0.20% N, in which a part of Cr is substituted by 1.0 to 7.0% Re according to necessary and the balance Fe with inevitable impurities and having excellent irradiation resistance. In the above alloy, as for the alloy components, the kind and the amt. to be added of each alloy element are determined so that the average bond order and the average (d) orbital electron level obtd. by bond orders, (d) orbital electron levels and atomic fractions with an Ni base metal will be regulated to specified value, by which the alloy components can be set. By using this alloy, the long service life of high temp.-high pressure structural members such as core members for a fast beeder reactor can be attained.
机译:目的:通过指定成分,获得具有优异的中子辐照性的Fe-Ni基奥氏体合金。由C,Si,Mn,Cr,Ni,Mo,W和Fe组成。组成:这种Fe-Ni基奥氏体合金是按重量计<= 0.2%C,<= 0.5%Si,<= 1.0%Mn,13%至18%Cr,30%至50%Ni,2.0%如果需要,可将6.0%Mo + W以及0.4至0.6 Mo /(Mo + W)进一步与0.10至0.30%Nb和<= 0.20%N混合,其中一部分Cr被1.0至7.0%取代according根据需要与余量的Fe具有不可避免的杂质并具有优异的耐辐照性。在上述合金中,合金成分的种类和数量。确定每种合金元素的添加量,以使平均键序和平均(d)轨道电子能级obtd。根据键序,将(d)镍基金属的轨道电子能级和原子分数调节到指定值,由此可以设定合金成分。通过使用这种合金,可以实现高温,高压结构部件,例如快速反应器的核心部件的使用寿命长。

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