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Al2O3 SINTER CERAMICS WITH REINFORCED HARD MATERIAL AND METHOD FOR THEIR PRODUCTION

机译:具有增强硬质材料的Al2O3烧结陶瓷及其生产方法

摘要

The invention pertains to the field of ceramics and relates to dense Al2O3 sinter ceramics with reinforced hard material of the Al2O3/TiCxNyOz type, such as those that can be used as wear-resisting parts. The aim of the invention is to provide Al2O3 sinter ceramics with reinforced hard material having a submicrometer structure in each individual phase. To this end, the structures of said Al2O3 sinter ceramics with reinforced hard material contain a corundum matrix with 0-15 vol. % ZrO2 and 0-15- vol. % of a hard material phase based on titanium TiCxNyOz with a) an oxygen content of z 0.10 or b) an oxygen content of z ≥ 0.05 and an evident substoichiometry of (x+y+z) ≤ 0.95 of the hard material phase, wherein the mean grain size in each individual phase in the structures is smaller than 1 νm and the structures can exhibit a high Vickers hardness of HV10 ≥ 2,100. Disclosed is also a method whereby the powder starting materials are crushed and mixed together in a liquid medium.
机译:本发明涉及陶瓷领域,并且涉及具有Al2O3 / TiCxNyOz类型的增强硬质材料的致密Al2O3烧结陶瓷,例如可以用作耐磨部件的那些。本发明的目的是提供具有在每个单独相中具有亚微米结构的增强硬质材料的Al 2 O 3烧结陶瓷。为此,具有增强的硬质材料的所述Al 2 O 3烧结陶瓷的结构包含0-15体积的刚玉基体。 ZrO2%和0-15-vol。基于钛TiCxNyOz的硬质材料相的百分比,其中a)硬质材料相的氧含量z> 0.10或b)硬质材料相的氧含量z≥0.05和明显的亚化学计量比(x + y + z)≤0.95,其中所述结构中每个相的平均晶粒尺寸小于1μm,并且所述结构可以表现出HV10≥2,100的高维氏硬度。还公开了一种将粉末原料粉碎并在液体介质中混合在一起的方法。

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