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DIAMOND AND OTHER HARD MATERIALS IN FIBRE REINFORCED CERAMIC MATRIX COMPOSITES

机译:纤维增强陶瓷基复合材料中的金刚石和其他硬质材料

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In this paper the development and manufacture of ceramic matrix composites (CMCs) which are suitable for grinding and cutting tools is described. Therefore, a long fibre reinforced composite material with a silicon carbide matrix bearing the hard material such as diamond or boron carbide was developed on the basis of the liquid silicon infiltration of carbon/carbon (LSI process). In a first step the hard particles were coated by matrix resin. Then sheets of preimpregnated C-fabrics and coated hard particles were laid up in a mould and subsequently consolidated by pressing or by using autoclave techniques. After pyrolysis of the polymer composite, the resulting porous C/C preform bearing the hard particles was infiltrated with liquid silicon yielding a SiC matrix, which bonds the C-fibres and hard particles tightly. This kind of composite has a sandwich like structure where the long C-fibres provide good strength and fracture toughness, whereas the hard particles offer excellent wear resistance and hardness. It is well known that diamond is prone to graphitization beyond 1200 deg C and easily reacts with liquid Si. It was found, however, that diamond was still present after LSI processing even at temperatures of 1650 deg C. Furthermore, the resulting CMCs as well as the intermediate products were characterized by microscopy and mechanical testing.
机译:在本文中,描述了适用于研磨和切割工具的陶瓷基复合材料(CMC)的开发和制造。因此,长纤维增强的碳化硅基质承载所述硬质材料,如金刚石或碳化硼碳/碳(LSI工艺)的液体渗硅的基础上发展起来的复合材料。在第一步中,通过基质树脂涂覆硬颗粒。然后在模具中铺设在模具中并通过压制或通过使用高压釜技术来铺设涂覆的C织物和涂覆的硬质颗粒。在聚合物复合材料的热解后,用液体硅渗透携带硬颗粒的所得多孔C / C预制件,得到SiC基质,其紧密地粘合C纤维和硬质颗粒。这种复合材料的具有像结构,其中长C-纤维提供良好的强度和断裂韧性的夹层,而硬质颗粒提供优异的耐磨性和硬度。众所周知,钻石容易出现超过1200℃的石墨化,并且容易与液体Si反应。然而,它发现,即使在1650℃的温度下,在LSI加工后仍存在钻石。此外,通过显微镜和机械测试表征所得的CMC以及中间产物。

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