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Construction for thermal color lead chen

机译:彩色热铅陈施工

摘要

A thermal-dye-bleach construction comprising a thermal nucleophile- generating agent in association with a styryl dye having a nucleus of general formula (I): ##STR1## representing the nucleus of a styryl dye in which R=methyl or ethyl groupPPY=alkoxy of 1 to 20 carbon atomsPPm=1 or 2,PPn=1, 2, or 3, and PPx.sup.⊖ =an anionPPThe aromatic fused benzene portion of the indolenine ring may be further substituted with commonly acceptable dye substituents such as alkyl and substituted alkyl (of 1 to 10 carbon atoms) groups, alkoxy groups (preferably of 1 to 10 carbon atoms), fused aromatic rings (as to make the benzene ring a fused naphthalene ring), halogen (including fluoro), cyano, nitro, carboxamido, amido, etc. One or two substituents chosen variously from said group may also be present on the phenyl ring to which the alkoxy group is attached. These substituents and their combinations should not be chosen so as to alter the absorption characteristics of the dye greatly enough to remove the maximum absorption from between 300 and 490 nm. X.sup.⊖ may be any anion, but certain classes of anions and certain particular anions are preferred. Aromatic and perfluorinated anions and, in particular dodecylbenzenesulfonate and especially perfluoro(ethylcyclohexane sulfonate) are preferred on account of their solubilizing power, but simpler anions such as iodide, chloride, bromide, methylsulfate, perchlorate and the like may also be used.
机译:一种热染料漂白结构,其包含与具有通式(I)核的苯乙烯基染料缔合的热亲核试剂,其中R =甲基或乙基的苯乙烯基核

Y = 1至20个碳原子的烷氧基

m = 1或2,

n = 1、2或3,

x .sup。⊖ =阴离子P吲哚环的芳族稠合苯部分可以进一步用通常可接受的染料取代基取代,例如烷基和取代的烷基(具有1至10个碳原子),烷氧基(优选1至10个碳原子)。 10个碳原子),稠合的芳环(使苯环成为稠合的萘环),卤素(包括氟),氰基,硝基,羧酰胺基,酰胺基等。也可以存在一个或两个选自所述基团的取代基在与烷氧基连接的苯环上。不应选择这些取代基及其组合,以使染料的吸收特性发生足够大的改变,以消除300至490 nm之间的最大吸收。 X.sup。⊖阴离子可以是任何阴离子,但是某些类别的阴离子和某些特定的阴离子是优选的。由于它们的增溶能力,优选芳族和全氟化的阴离子,特别是十二烷基苯磺酸盐,尤其是全氟(乙基环己烷磺酸盐),但是也可以使用更简单的阴离子,例如碘离子,氯离子,溴离子,甲基硫酸根,高氯酸根等。

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