首页> 外国专利> METHOD OF SELECTIVELY CHEMICALLY CHANGING INSIDE OF INORGANIC MATERIAL AND INORGANIC MATERIAL INSIDE OF WHICH IS SELECTIVELY CHEMICALLY CHANGED

METHOD OF SELECTIVELY CHEMICALLY CHANGING INSIDE OF INORGANIC MATERIAL AND INORGANIC MATERIAL INSIDE OF WHICH IS SELECTIVELY CHEMICALLY CHANGED

机译:选择性化学变化的无机材料内部和无机材料内部的化学变化方法

摘要

An inorganic material (3) containing rare-earth ions and/or transition metal ions is irradiated with a pulse laser beam (1) whose focal point (2) is inside the inorganic material (3). The inorganic material is a glass or crystal consisting of one or more of oxides, halides, and chalcogenides. The rare-earth ions include ions such as of Ce, Nd, Pr, Sm, Eu, Tb, Dy, Tm, and Tb. The transition metal ions include ions such as of Ti, Mn, Cr, V, Fe, Cu, Mo, and Ru. When the focal point (2) of the pulse laser beam (1) is moved relative to the inorganic material (3), a region of predetermined pattern where the ionic valences have changed is formed inside the inorganic material (3). The pulse laser beam preferably has a pulse width of below 1 picosend. Though the valences of the rare-earth or transition metal ions change at and around the focal point (2), they do not change in the other regions. Therefore a chemically changed region of necessary pattern is formed inside the inorganic material (3). Such a processed inorganic material has a specific region thereinside where optical characteristics are selectively changed, and hence is used as, e.g., a memory material featured by the changed optical characteristics and a functional material for light-emitting devices.
机译:用焦点(2)在无机材料(3)内部的脉冲激光束(1)照射含有稀土离子和/或过渡金属离子的无机材料(3)。无机材料是由氧化物,卤化物和硫属化物中的一种或多种组成的玻璃或晶体。稀土离子包括诸如Ce,Nd,Pr,Sm,Eu,Tb,Dy,Tm和Tb的离子。过渡金属离子包括诸如Ti,Mn,Cr,V,Fe,Cu,Mo和Ru的离子。当脉冲激光束(1)的焦点(2)相对于无机材料(3)移动时,在无机材料(3)的内部形成离子化合价已改变的预定图案的区域。脉冲激光束优选具有小于1皮欧森德的脉冲宽度。尽管稀土金属或过渡金属离子的化合价在焦点(2)或附近发生变化,但在其他区域中不变。因此,在无机材料(3)的内部形成必要图案的化学变化区域。这种经处理的无机材料在其内部具有选择性地改变光学特性的特定区域,因此用作例如以改变的光学特性为特征的存储材料和用于发光装置的功能材料。

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