(wherein R1 is a lower alkyl group), the method for the formation of carbon-carbon bond comprising conducting a reaction in the presence of the said catalyst and the method for an addition reaction of an α-halogeno carboxylic acid derivative to an unsaturated compound comprising using the said catalyst."/> An azo compound as a catalyst for formation of a carbon-carbon bond and a method for the formation of such a bond
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An azo compound as a catalyst for formation of a carbon-carbon bond and a method for the formation of such a bond

机译:用作形成碳-碳键的催化剂的偶氮化合物及其形成方法

摘要

To provide a catalyst for the formation of a carbon-carbon bond which can control side reactions under mild reaction conditions and also stereoregularity, to provide a method for the formation of a carbon-carbon bond using the said catalyst and to provide a method for an addition reaction using the said catalyst.;The catalyst for the formation of a carbon-carbon bond comprising an azo compound shown by the general formula [1] (wherein R1 is a lower alkyl group), the method for the formation of carbon-carbon bond comprising conducting a reaction in the presence of the said catalyst and the method for an addition reaction of an α-halogeno carboxylic acid derivative to an unsaturated compound comprising using the said catalyst.
机译:提供一种形成碳-碳键的催化剂,该碳-碳键可以控制温和的反应条件下的副反应以及立构规整度,提供一种使用所述催化剂形成碳-碳键的方法,并提供一种用于形成碳-碳键的方法。使用上述催化剂进行的加成反应。形成通式[1]所示的包含偶氮化合物的碳-碳键的催化剂。 <图像文件=“ IMGA0001.GIF” he =“ 30” id =“ ia01” imgContent =“ chem” imgFormat =“ GIF” wi =“ 78” /> (其中R 1 是低级烷基),形成碳-碳键的方法包括在所述催化剂的存在下进行反应,以及α-卤代羧酸的加成反应的方法。包括使用所述催化剂的不饱和化合物的酸衍生物。

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