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Growth method of grain refinement of mixed fuel sintered body using lithium oxide

机译:氧化锂细化混合燃料烧结体晶粒长大的方法

摘要

The present invention relates to a mixture or the like when the valence of +3 cation compound containing Ga element CeO 2, PuO 2, Gd 2 O 3, Er 2 O 3 to promote sintering of the mixed powder material in a reducing sintering conditions and UO 2 When Li 2 O is used and pure UO 2 is sintered under ordinary sintering conditions to obtain a sintered body having an average grain size of 100 μm or more, Li 2 O is used as a sintering accelerator.;In the preparation of mixed fuel sintered body, 0.1wt% Li 2 O is added to the mixed powder. When the sintered density is rather low at 1580 ℃ or more and the coarse sintered body is desired, sintering is performed in a mixed gas atmosphere of hydrogen and argon. And sintered body having a grain size slightly smaller than that is sintered in a pure hydrogen atmosphere, a desired sintered body can be obtained.
机译:本发明涉及当含有Ga元素 CeO 2,PuO 2,Gd 2 O 3,Er 2 O 3的+3阳离子化合物的化合价促进混合粉末的烧结时的混合物等。还原性烧结条件下的材料和UO 2 使用Li 2 O并在普通烧结条件下烧结纯UO 2 以获得烧结体Li 2 O被用作烧结促进剂,其平均粒径为100μm以上;在混合燃料烧结体的制备中,Li 2 将O添加到混合粉末中。当烧结密度在1580℃或更高时相当低并且需要粗大的烧结体时,在氢和氩的混合气体气氛中进行烧结。并且,具有比在纯氢气氛中烧结的粒径稍小的粒径的烧结体,可以得到所期望的烧结体。

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