METHOD OF COMBINED PREPARATION OF MONOCYCLOALKYLDIHYDRO60 FULLERENES AND BISCYCLOALKYLTETRAHYDRO 60 FULLERENES

摘要

FIELD: fine organic synthesis, more particularly original semiproducts for preparing biological active agents for medicine and agriculture, and addition agents for oils. SUBSTANCE: method comprises reacting toluene solution of C₆₀ fullerene with excessive amount of ether solution of α,ω-dimagnesium bromide, in the presence of catalyst under normal conditions for 8-24 hours and subsequently treating reaction mixture with 5% aqueous hydrochloric acid. Combined yield of final products is 56-92%. EFFECT: more efficient preparation method. 1 ex, 1 tbl