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Optically active bidentate phosphine ligand palladium complex

机译:光学活性双齿膦膦配体钯配合物

摘要

The present invention provides a novel optically active bidentate phosphine ligand palladium complex of formula (I) or (II) which can be used for the preparation of optically active &bgr;-hydroxyketones: ##STR1## [wherein Y.sup.- represents an anion pair which may form sa X represents ##STR2## {wherein R.sup.1 represents hydrogen atom, C.sub.1- 6 alkyl group, C.sub.1-6 alkoxyl group, cyano group, nitro group, halogen atom or phenyl group, etc.; m represents 1 or 2; when m is 2, two R.sup.1 s may be same or different}; andPPA and B each independently represents phenyl group or cyclohexyl group {said phenyl group and cyclohexyl group each is unsubstituted or substituted by R.sup. 2 (R.sup.2 has the same meaning as defined in R.sup.1)}).
机译:本发明提供了式(I)或(II)的新型旋光性二齿膦配体钯配合物,其可用于制备旋光性β-羟基酮:其中,Y代表-。可能形成盐的阴离子对; X代表## STR2 ## {其中R 1代表氢原子,C 1-6烷基,C 1-6烷氧基,氰基,硝基,卤素原子或苯基,等等。; m表示1或2;当m为2时,两个R s可以相同或不同} P A和B分别独立地表示苯基或环己基(所述苯基和环己基均未被取代或被R s取代。 2(R.2具有与R.1中定义相同的含义)})。

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