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Optically active bidentate phosphine ligand palladium complex
Optically active bidentate phosphine ligand palladium complex
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机译:光学活性双齿膦膦配体钯配合物
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摘要
The present invention provides a novel optically active bidentate phosphine ligand palladium complex of formula (I) or (II) which can be used for the preparation of optically active &bgr;-hydroxyketones: ##STR1## [wherein Y.sup.- represents an anion pair which may form sa X represents ##STR2## {wherein R.sup.1 represents hydrogen atom, C.sub.1- 6 alkyl group, C.sub.1-6 alkoxyl group, cyano group, nitro group, halogen atom or phenyl group, etc.; m represents 1 or 2; when m is 2, two R.sup.1 s may be same or different}; andPPA and B each independently represents phenyl group or cyclohexyl group {said phenyl group and cyclohexyl group each is unsubstituted or substituted by R.sup. 2 (R.sup.2 has the same meaning as defined in R.sup.1)}).
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