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Pitch carbon fiber spinning organic metal-containing mesophase pitch

机译:沥青碳纤维纺丝含有机金属的中间相沥青

摘要

PURPOSE: To provide a new method for producing a unique metal-containing isotropic pitch material that is suitable for production of carbon fiber. ;CONSTITUTION: A soluble aromatic organometallic compound is added to a carbon starting material that is substantially defective in the meso phase pitch, the resultant mixture is subjected to the heat soaking to give the isotropic pitch containing mesogen and soluble organometallic compound. Then, the pitch products are subjected to the solvent separation to separate the mesodiene containing the metal from the organometallic compound. This metal-containing mesogen is heated up to sufficiently elevated temperature and fused to form the metal-containing mesophase pitch. In another process, the carbon starting material is thermally soaked to form isotropic pitch product containing mesogen. A high-molecular-weight soluble aromatic organometallic compound is added to the mesogen-containing isotropic pitch product, then subjected to the solvent separation. The metal-containing carbon fiber produced from the mesophase pitch shows increased stability and tensile strength. Alternatively, the solvent fractionation or separation is carried out under supercritical conditions to form metal-containing mesophase pitch. The formulation of the organometallic compound to the carbon source may be done either of before or after thermal soaking.;COPYRIGHT: (C)1999,JPO
机译:目的:提供一种新的方法来生产适合于碳纤维生产的独特的含金属各向同性沥青材料。组成:将可溶的芳族有机金属化合物添加到中间相沥青中基本有缺陷的碳原料中,将所得混合物进行热浸处理,得到含有介晶和可溶有机金属化合物的各向同性沥青。然后,对沥青产物进行溶剂分离以将含有金属的the二烯与有机金属化合物分离。将该含金属的液晶元加热到足够高的温度,并熔融形成含金属的中间相沥青。在另一种方法中,将碳起始材料热浸以形成含有介晶的各向同性沥青产品。将高分子量的可溶性芳族有机金属化合物加入到含液晶元的各向同性沥青产品中,然后进行溶剂分离。由中间相沥青产生的含金属的碳纤维显示出增加的稳定性和拉伸强度。或者,在超临界条件下进行溶剂的分馏或分离以形成含金属的中间相沥青。有机金属化合物与碳源的配制可以在热浸之前或之后进行。版权所有:(C)1999,JPO

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