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Production manner null of separable manner of the (m nitrophenyl) alkylamine and the (p nitrophenyl) alkylamine, and the (m aminophenyl) alkylamine and the (p aminophenyl) alkylamines which use
Production manner null of separable manner of the (m nitrophenyl) alkylamine and the (p nitrophenyl) alkylamine, and the (m aminophenyl) alkylamine and the (p aminophenyl) alkylamines which use
PURPOSE: To separate the subject compound useful as a polyimide, etc., efficiently and in high yield by converting a mixture containing m-derivative and p- derivative of a specific -nitrophenylalkylamine into a sulfate and crystallizing the p-derivative. ;CONSTITUTION: A mixture containing at least m-derivative and p-derivative of an -(nitrophenyl)alkylamine of the formula (R is H or 1-5C lower alkyl; nitro group is in m-position or p-position) is converted into a sulfate, the p- derivative is preferentially crystallized to separate the p-derivative from the m-derivative. The prepared -(m-nitrophenyl)alkylamine or -(p-nitrophenyl) alkylamine (sulfate) is catalytically reduced in particular to give an -(m- aminophenyl)alkylamine or an -(p-aminophenyl)alkylamine.;COPYRIGHT: (C)1994,JPO&Japio
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