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Triphenylamine derivatives, charge transporting materials and an electrophotographic photoreceptor using the same

机译:三苯胺衍生物,电荷输送材料和使用其的电子照相感光体

摘要

PURPOSE: To obtain a new compound, good in solubility in a binder polymer without causing the deposition of a crystal or formation of a pinhole and useful as a charge transport material capable of manifesting high carrier mobility and providing a photoreceptor having a high sensitivity and a low residual potential. ;CONSTITUTION: This compound is expressed by formula I (R1 to R5 each is H, a lower alkyl, an alkoxy, a halogen or an aryl which may have a substituent group or R1 and R2 and R3 and R4 each may mutually be bound to form rings; n is 0 or 1), e.g. 4,4'-bis(4",4"-diphenyl-1",3"-butadienyl)triphenylamine. The compound expressed by formula I in which n is 1 is obtained by reacting a 4,4'- diformyltriphenylamine derivative expressed by formula II with a dialkyl 3,3- diarylallylphosphite expressed by formula III (R6 is a lower alkyl) in a molar amount of 2 times based on the compound expressed by formula II in the presence of a base at a temperature of ambient temperature to about 80°C.;COPYRIGHT: (C)1995,JPO
机译:用途:为了获得一种新的化合物,它在粘合剂聚合物中的溶解性良好,而不会导致晶体沉积或形成针孔,并且可用作电荷传输材料,能够表现出高的载流子迁移率并提供具有高灵敏度和高灵敏度的感光体。剩余电位低。 ;组成:该化合物用式I表示(R 1 至R 5 分别为H,低级烷基,烷氧基,卤素或可具有取代基或R 1 和R 2 和R 3 和R 4 可以相互结合形成环; n为0或1),例如4,4'-双(4“,4”-二苯基-1“,3”-丁二烯基)三苯胺。通过使式II表示的4,4'-二甲酰基三苯胺衍生物与式III表示的二烷基3,3-二芳基烯丙基亚磷酸酯反应,得到n为1的式I表示的化合物(R 6 为在室温下至约80°C的温度下,在碱存在下,相对于式II表示的化合物而言,其摩尔量是式II表示的化合物的2倍;版权所有:(C)1995,JPO

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