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FURFURYL ALCOHOL MIXTURES FOR USE AS CLEANING AGENTS

机译:呋喃基醇混合物作为清洁剂

摘要

The present invention offers an alternative to thechlorofluorocarbons which have been used in the cleaningindustry. In particular, the present invention uses asolution having tetrahydrofurfuryl alcohol (THFA) and anactivator. As activators, compounds of the formula(See formula I)wherein R1, R2 and R3 are independently hydrogen, C1-C7alkyl, C5-C6 cycloalkyl, furanyl which can be substitutedby C1-C7 alkyl, tetrahydrofuranyl which can be substitutedby C1-C7 alkyl, pyrrolyl, pyrrolidinyl, benzyl which can besubstituted by C1-C7 alkyl, phenyl which can be substitutedby C1-C7 alkyl, C1-C7 alkenyl, C1-C7 alkynl, furfuryl whichcan be substituted by C1-C7 alkyl, or tetrahydrofurfurylwhich can be substituted by C1-C7 alkyl, wherein R1, R2 andR3 can be substituted by at least one hydroxy group,provided that R1, R2 and R3 are not simultaneouslyhydrogen, orwherein R4 is hydrogen, C1-C6 alkyl, C5-C6 cycloalkyl,furanyl which can be substituted by C1-C6 alkyl,tetrahydrofuranyl which can be substituted by C1-C6 alkyl,pyrrolyl, pyrrolidinyl, or benzyl which can be substitutedby C1-C6 alkyl, R5 is C1-C6 alkyl, C5-C6 cycloalkyl,furanyl which can be substituted by C1-C6 alkyl,tetrahydrofuranyl which can be substituted by C1-C6 alkyl,furfuryl which can be substituted by C1-C6 alkyl,tetrahydrofurfuryl which can be substituted by C1-C6 alkyl,pyrrolyl, pyrrolidinyl, benzyl which can be substituted byC1-C6 alkyl, or the group-(C)a -O-(C)b -O-(C)b -OH20wherein a is from 1 to 3 and b is from 1 to 4, can be used.In addition to the activators (I) or (II), the presentinvention can also include as activators cyclic or non-cyclic diamines, pyrrolidone, which can be substituted byC1-C6 alkyl or C1-C6 alkenyl, or butyrolactone.
机译:本发明提供了一种替代方案。清洁中使用的氯氟烃行业。特别地,本发明使用四氢糠醇(THFA)和激活剂。作为活化剂,下式的化合物(参见公式I)其中R1,R2和R3独立地是氢,C1-C7可以被取代的烷基,C5-C6环烷基,呋喃基被可被取代的C1-C7烷基四氢呋喃基由C1-C7的烷基,吡咯基,吡咯烷基,苄基组成被可被取代的C1-C7烷基,苯基取代由C 1 -C 7烷基,C 1 -C 7烯基,C 1 -C 7炔基,糠基组成可以被C1-C7烷基或四氢糠基取代可以被C1-C7烷基取代,其中R1,R2和R3可以被至少一个羟基取代,前提是R1,R2和R3不同时氢,或其中R4是氢,C1-C6烷基,C5-C6环烷基,可以被C1-C6烷基取代的呋喃基可以被C1-C6烷基取代的四氢呋喃基,可以被取代的吡咯基,吡咯烷基或苄基在C 1 -C 6烷基中,R 5是C 1 -C 6烷基,C 5 -C 6环烷基,可以被C1-C6烷基取代的呋喃基可以被C1-C6烷基取代的四氢呋喃基,可以被C1-C6烷基取代的糠基,可以被C1-C6烷基取代的四氢糠基,可以被以下取代的吡咯基,吡咯烷基,苄基C1-C6烷基或基团-(C)a -O-(C)b -O-(C)b -OH20其中a为1-3,b为1-4。除活化剂(Ⅰ)或(Ⅱ)外,本本发明还可包括环状或非环状作为活化剂。可以被下列取代的环状二胺吡咯烷酮C 1 -C 6烷基或C 1 -C 6烯基或丁内酯。

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