Inert anode containing oxides of nickel, iron and cobalt useful for the electrolytic production of metals

摘要

An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe2O3 and CoO. The inert anode composition may comprise the following mole fractions of NiO, Fe2O3 and CoO: 0.15 to 0.99 NiO; 0.0001 to 0.85 Fe2O3; and 0.0001 to 0.45 CoO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni-Fe-Co-O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.