首页> 外国专利> Optimized process for the production of catalyst supports based on silica gel as well as chromium catalysts supported on silica gel

Optimized process for the production of catalyst supports based on silica gel as well as chromium catalysts supported on silica gel

机译:用于生产基于硅胶的催化剂载体以及负载在硅胶上的铬催化剂的优化工艺

摘要

The invention relates to a catalyst support and a method for the production of said catalyst support comprising: a) production of a 10 to 25 weight % solid (calculated as SiO2) containing silicic acid-hydro gels whose particles are essentially sphere-shaped; b) extraction of the hydrogel-particles using alcohol until at least 60 % of the water contained in the hydrogel is removed, c) drying the hydrogel so obtained, at a temperature of /= 160 DEG C at normal pressure and subsequent treatment of said hydrogel with an inert carrier gas until the remaining alcohol content is less than 10 weight % (xerogel-formation); d) adjustment of said xerogel particle size so obtained to the desired particle size, whereby the hydrogel particle have a particle size of /= 8 mm prior to extraction. The invention also relates to a catalyst and a method for the production ofsaid catalyst by loading the catalyst support with chromium compounds. The invention further relates to a method for the production of polyolefins using said catalyst.
机译:本发明涉及一种催化剂载体和制备所述催化剂载体的方法,该方法包括:a)制备其颗粒基本为球形的含10-25重量%固体(以SiO 2计)的硅酸-水凝胶; b)用醇萃取水凝胶颗粒,直到除去水凝胶中至少60%的水为止,c)在常温下在> / = 160℃的温度下干燥如此获得的水凝胶,然后进行水处理。具有惰性载气的所述水凝胶,直到剩余的醇含量小于10重量%(形成干凝胶); d)将如此获得的所述干凝胶粒度调节至所需粒度,由此在提取之前,水凝胶颗粒的粒度≥8mm。本发明还涉及通过在催化剂载体中负载铬化合物来生产所述催化剂的催化剂和方法。本发明进一步涉及一种使用所述催化剂生产聚烯烃的方法。

著录项

  • 公开/公告号DE19943166A1

    专利类型

  • 公开/公告日2001-03-15

    原文格式PDF

  • 申请/专利权人 ELENAC GMBH;

    申请/专利号DE19991043166

  • 申请日1999-09-09

  • 分类号C08F4/02;C08F10/00;C08F4/22;

  • 国家 DE

  • 入库时间 2022-08-22 01:10:17

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