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Method for synthesizing perfluorosulfonamide, persulfonimide and salts thereof, and sulfonylating reagent

机译:全氟磺酰胺,全磺酰亚胺及其盐和磺酰化试剂的合成方法

摘要

The invention concerns a method of sulphonation characterised in that it consists in contacting a nucleophile whose nucleophilic atom is a nitrogen atom with a reagent comprising by successive or simultaneous addition: a heavy sulphonyl halide (i.e. whose atomic number is not less than that of chlorine), advantageously suphonyl chloride; and an organic base both not capable of alkylation and lipid soluble; and the organic part of said sulphonyl is perfluorinated on the carbon carried by the sulphur. The invention is applicable to organic synthesis.
机译:本发明涉及一种磺化方法,其特征在于,其使亲核原子为氮原子的亲核试剂与包含通过连续或同时添加的试剂接触:重磺酰卤(即,其原子序数不小于氯原子序数) ,有利地是磺酰氯;以及既不能烷基化又不能脂溶的有机碱;所述磺酰基的有机部分在硫携带的碳上全氟化。本发明适用于有机合成。

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