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CdZnMS photocatalyst including cations for water decomposition and preparation thereof and method for producing hydrogen by use of the same

机译:包含用于水分解的阳离子的CdZnMS光催化剂及其制备方法和使用该催化剂制备氢的方法

摘要

Present invention relates to a CdZnMS photocatalyst for producing hydrogen from water and a method for preparing thereof and a method for producing hydrogen by using said photocatalyst. Said photocatalyst is characterized by the following general formula VII:; PTEXTPDATm(a)/Cd/PDATHILSBPDATx/PDAT/SB/HILPDATZn/PDATHILSBPDATy/PDAT/SB/HILPDATM/PDATHILSBPDATz/PDAT/SB/HILPDATS  (VII)/PDAT/PTEXT ;wherein m represents at least one doped metal element as an electron acceptor selected from the group consisting of Ni, Pt, Ru and the oxidized compound of these metals; a represents a % by weight of m, ranging from 0.10 to 5.00; M is a catalyst element selected from the group consisting of Mo, V, Al, Cs, Mn, Fe, Pd, Pt, P, Cu, Ag, Ir, Sb, Pb, Ga and Re. z represents an atom % of M/(CdZnM), ranging from 0.05 to 20.00 and x and y represent an atom % of Cd/(CdZnM) and an atom % of Zn/(CdZnM), ranging from 10.00 to 90.00, respectively.
机译:由水生产氢气的CdZnMS光催化剂及其制备方法和使用该光催化剂生产氢气的方法技术领域本发明涉及一种由水生产氢气的CdZnMS光催化剂及其制备方法和使用该光催化剂生产氢气的方法。所述光催化剂的特征在于以下通式VII: <数学> <![CDATA [ m(a)/ Cd x Zn y M z S(VII) ]]> ;其中m表示选自Ni,Pt,Ru和这些金属的氧化的化合物中的至少一种作为电子受体的掺杂金属元素; a表示m的重量%,范围为0.10至5.00。 M是选自Mo,V,Al,Cs,Mn,Fe,Pd,Pt,P,Cu,Ag,Ir,Sb,Pb,Ga和Re的催化剂元素。 z代表M /(CdZnM)的原子%,范围为0.05至20.00,x和y分别代表Cd /(CdZnM)的原子%和Zn /(CdZnM)的原子%,范围为10.00至90.00。

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