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Process for producing lactide and process for producing polylactic acid from fermented lactic acid employed as starting material

机译:丙交酯的生产方法和由发酵乳酸作为起始原料生产聚乳酸的方法

摘要

According to the present invention, a process for consistently producing lactide from ammonium lactate obtained by lactic fermentation, and a process for consistently producing polylactic acid from ammonium lactate obtained by lactic fermentation, are provided. A process for producing lactide, which comprises the steps of: (1) synthesizing lactate ester from ammonium lactate obtained by lactic fermentation; (2) polycondensing the lactate ester in the presence of a catalyst other than monobutyltin, whereby polylactic acid with a weight-average molecular weight of less than 15,000 (lactic acid prepolymer) is synthesized; and (3) depolymerizing the polylactic, whereby lactide is produced. A process for producing polylactic acid, which comprises the additional step of (4) ring-opening polymerizing said lactide, whereby polylactic acid is obtained. A process for producing lactate ester from ammonium lactate obtained by lactic fermentation.
机译:根据本发明,提供了一种由通过乳酸发酵获得的乳酸铵恒定地生产丙交酯的方法,以及从由乳酸发酵获得的乳酸铵恒定地生产聚乳酸的方法。丙交酯的制造方法,其包括以下步骤:(1)由通过乳酸发酵得到的乳酸铵合成乳酸酯。 (2)在单丁基锡以外的催化剂存在下使乳酸酯缩聚,合成重均分子量小于15,000的聚乳酸(乳酸预聚物)。 (3)使聚乳酸解聚而生成丙交酯。一种制备聚乳酸的方法,该方法包括以下附加步骤:(4)使所述丙交酯开环聚合,从而获得聚乳酸。由乳酸发酵获得的乳酸铵生产乳酸酯的方法。

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