首页> 外国专利> AN ENERGETIC PLACITIZER COMPRISING A EUTETIC MIXTURE OF BIS(2,2-DINITROPROPYL)FORMAL, 2,2-DINITROPROPYL 2,2-DINITROBUTYL FORMAL AND BIS(2,2-DINITROBUTYL)FORMAL, AND A PREPARATION METHOD THEREOF

AN ENERGETIC PLACITIZER COMPRISING A EUTETIC MIXTURE OF BIS(2,2-DINITROPROPYL)FORMAL, 2,2-DINITROPROPYL 2,2-DINITROBUTYL FORMAL AND BIS(2,2-DINITROBUTYL)FORMAL, AND A PREPARATION METHOD THEREOF

机译:包含BIS(2,2-二硝基丙基)甲醛,2,2-二硝基丙基2,2-二硝基甲醛和BIS(2,2-二硝基丁基)甲醛的全脂混合物的能量缓和剂及其制备方法

摘要

An energetic plascitizer comprising bis(2,2-dinitropropyl) formal, 2,2-dinitropropyl 2,2-dinitrobutyl formal and bis 2,2-dinitrobutyl) formal in a molar ratio of 20~68%/28~50%/4~30% is, described. It is also provided a method for synthesizing the plasticizer comprising: dissolving 2,2-dinitropropanol and 2,2-dinitrobutanol into an organic solvent to form an organic solution, in which the molar ratio of 2,2-dinitropropanol to 2,2-dinitrobutanol is 3:1-6:1; adding to the organic solution a sulfuric acid solution where formaldehyde source was dissolved, wherein the temperature of reaction medium is maintained below 20° C.; and separating and purifying the product from the reaction mixture.The plascitizer according to the present invention has an excellent thermal and chemical properties while incurring a low production cost. Especially, the energy content of the plasticizer of the present invention is heightened by minimizing the content of the diformal generated as a side product, so that it is favorably adapted for use in an insensitive high performance explosive and a propellant.
机译:一种高能增塑剂,其摩尔比为20〜68%/ 28〜50%/ 4,包括双(2,2-二硝基丙基)甲醛,2,2-二硝基丙基2,2-二硝基丁基甲醛和双2,2-二硝基丁基甲醛)描述了〜30%。还提供了合成增塑剂的方法,该方法包括:将2,2-二硝基丙醇和2,2-二硝基丁醇溶解在有机溶剂中以形成有机溶液,其中2,2-二硝基丙醇与2,2-的摩尔比。二硝基丁醇为3:1-6:1;向有机溶液中加入溶解甲醛源的硫酸溶液,使反应介质的温度保持在20℃以下。本发明的增塑剂具有优异的热和化学性质,同时降低了生产成本。尤其是,通过使作为副产物而产生的二甲醛的含量最小化来提高本发明的增塑剂的能量含量,从而使其适合用于不敏感的高性能炸药和推进剂中。

著录项

  • 公开/公告号KR100381133B1

    专利类型

  • 公开/公告日2003-04-23

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20000018625

  • 申请日2000-04-10

  • 分类号C06B25/00;

  • 国家 KR

  • 入库时间 2022-08-21 23:45:29

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