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Method of evaluating the catalytic activity of a rare earth alkoxide

机译:评估稀土醇盐催化活性的方法

摘要

This invention provides a method of evaluating the catalytic activity of a rare earth alkoxide used as a starting material of a basic catalyst or an asymmetric synthesis catalyst. The rare earth alkoxide used as the subject of evaluation and 2,2′-dihydroxy-1,1′-binaphthol are used as the starting material to prepare a rare earth complex catalyst which is then used to conduct the asymmetric epoxidation of an enone. The epoxy enone formed by this reaction, the unreacted enone, and the enantiomeric excess are measured, and from these results, the catalytic activity of the rare earth alkoxide is evaluated.
机译:本发明提供了一种评价用作碱性催化剂或不对称合成催化剂的起始原料的稀土醇盐的催化活性的方法。用作评价对象的稀土醇盐和2,2′-二羟基-1,1′-二萘酚用作起始原料,以制备稀土配合物催化剂,然后将其用于烯酮的不对称环氧化。测量通过该反应形成的环氧烯酮,未反应的烯酮和对映异构体过量,并从这些结果评估稀土醇盐的催化活性。

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