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Photocurable composition, process for producing photocurable resin, and crosslinked product
Photocurable composition, process for producing photocurable resin, and crosslinked product
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机译:光固化性组合物,光固化性树脂的制造方法以及交联物
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摘要
A photocurable composition is provided which yields an excellent tack-free, hard cured product without any addition of photoinitiators. A photocurable composition which is excellent in storage stability is also provided. The photocurable composition contains a resin having an acryloyl group and a chemical structure element selected from the group consisting of &bgr;-diketone groups and &bgr;-ketoester groups, wherein the &bgr;-diketone group or the &bgr;-ketoester group has a tetra-substituted carbon atom between two carbonyl groups, which is capable of generating one or two free radicals under photoirradiation, and the photocurable composition does not increase more than 25% in viscosity when heated at 60° C. for 5 days.
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机译:提供了可光固化的组合物,其在不添加任何光引发剂的情况下产生了优异的无粘性,硬固化的产品。还提供了储存稳定性优异的光固化性组合物。光固化性组合物包含具有丙烯酰基的树脂和选自由-b-二酮基和b-酮酸酯基组成的组中的化学结构元素,其中-b-二酮基或-b-酮酸酯基具有四-在两个羰基之间的取代的碳原子,其能够在光辐照下产生一个或两个自由基,并且当在60℃下加热时,该光固化性组合物的粘度增加不超过25%。 C. 5天。
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