Research on the Mechanism of Accelerator for Photocurable Resin in 3D Printing

摘要

The photopolymerization kinetics of cycloaliphatic epoxide and oxetane with accelerators were investigated with Real-time Fourier transform infrared spectroscopy (RT-FTIR). The consumption rates of epoxy group and oxetane group as a function of time were obtained by monitoring of the absorption peaks in the 789 cm-1 and 981 cm-1. The effect of accelerators type and the accelerating mechanism were discussed. In general, benzyl alcohol and its analogues with electron-donating substituents are useful accelerators for the cationic polymerization of cycloaliphatic epoxide and oxetane. Activated monomer mechanism and free-radical chain-induced decomposition of onium salt cationic photoinitiator account for the observed accelerating effect on the polymerization rate.