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Photocurable composition, process for producing photocurable resin, and crosslinked product

机译:光固化性组合物,光固化性树脂的制造方法以及交联物

摘要

A photocurable composition is provided which yields an excellent tack-free, hard cured product without any addition of photoinitiators. A photocurable composition which is excellent in storage stability is also provided. The photocurable composition contains a resin having an acryloyl group and a chemical structure element selected from the group consisting of β-diketone groups and β-ketoester groups, wherein the β-diketone group or the β-ketoester group has a tetra-substituted carbon atom between two carbonyl groups, which is capable of generating one or two free radicals under photoirradiation, and the photocurable composition does not increase more than 25% in viscosity when heated at 60°C for 5 days.
机译:提供了可光固化的组合物,其在不添加任何光引发剂的情况下产生了优异的无粘性,硬固化的产品。还提供了储存稳定性优异的光固化性组合物。光固化性组合物包含具有丙烯酰基的树脂和选自β-二酮基和β-酮酸酯基的化学结构元素,其中β-二酮基或β-酮酸酯基具有四取代的碳原子。在两个羰基之间存在一个可在光辐射下产生一个或两个自由基的基团,并且当在60°C加热5天时,光固化性组合物的粘度增加不超过25%。

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