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IMPROVED COMPOSITION OF A SELECTIVE OXIDATION CATALYST FOR USE IN FUEL CELLS

机译:用于燃料电池的选择性氧化催化剂的改进组成

摘要

This invention pertains to improved formulations of platinum-molybdenum alloys for use as anode catalysts. These electrocatalysts find utility as a constituent of gas diffusion electrodes for use in fuel cells that operate at less than 180 DEG C. or in applications whereupon hydrogen is oxidized in the presence of carbon monoxide or other platinum inhibiting substances. The new formulations derive unexpected activity through creating highly dispersed alloy particles of up to approximately 300 ANGSTROM on carbon supports. The desired activity is achieved by carefully controlling the platinum to molybdenum ratio during preparation and judiciously selecting a proper loading of alloy on the carbon support.
机译:本发明涉及用作阳极催化剂的改进的铂钼合金配方。这些电催化剂可用作气体扩散电极的组成部分,用于在低于180℃工作的燃料电池中或在一氧化碳或其他铂抑制物质存在下氢被氧化的应用中。这些新配方通过在碳载体上产生高达约300埃的高度分散的合金颗粒而获得了意想不到的活性。通过在制备过程中仔细控制铂与钼的比例并明智地选择碳载体上合适的合金负载量,可以实现所需的活性。

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