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METHOD FOR DISPOSAL OF LIQUID RADIOACTIVE WASTES IN DEEP RESERVOIR BEDS (ALTERNATIVES)

机译:深储层中液体放射性废物处置的方法(替代品)

摘要

FIELD: immobilizing liquid radioactive wastes. SUBSTANCE: method includes analysis of chemical composition of wastes to find concentration of most easily hydrolyzed Fe(III) cation in them and their chemical treatment by complexing composition out of range of carbonic acids or oxyacids depending on Fe(III) concentration. With Fe(III) concentration between 50 and 250 mg/l mole proportion of Fe(III) and of complexing compound is 1 : 7. With Fe(III) concentration higher than 250 mg/l mole proportion of Fe(III) and of complexing compound is 1 : 10. In this case pH is corrected to 1-3. With Fe(III) concentration below 50 mg/l pH is corrected to 1-1.5 and wastes are not treated with complexing compound. Prior to injecting liquid radioactive wastes reservoir bed is treated with solution incorporating 1.0-6.0 g/l of nitric acid, its amount being 10-15% of radioactive waste volume. EFFECT: enhanced safety of radioactive waste disposal. 8 cl, 3 dwg, 1 tbl
机译:领域:固定液态放射性废物。物质:该方法包括分析废物的化学组成,以找出废物中最易水解的Fe(III)阳离子的浓度,并通过根据Fe(III)浓度超出碳酸或含氧酸的范围络合其组成对废物进行化学处理。 Fe(III)的浓度在50至250 mg / l摩尔比例的Fe(III)与络合化合物为1:7。Fe(III)的浓度高于250 mg / l摩尔比例的Fe(III)和络合物络合化合物为1:10。在这种情况下,pH值校正为1-3。当Fe(III)的浓度低于50 mg / l时,pH值将校正为1-1.5,并且不使用络合物处理废物。在注入液态放射性废物之前,储液床要经过掺有1.0-6.0 g / l硝酸的溶液处理,其量为放射性废物体积的10-15%。效果:提高了放射性废物处置的安全性。 8厘升,3载重吨,1桶

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