首页> 外国专利> Polyoxyalkylene monoalkyl ether, process for producing the same, polymerizable polyoxyalkylene monoalkyl ether derivative, polymer of said derivative and dispersant comprising said polymer

Polyoxyalkylene monoalkyl ether, process for producing the same, polymerizable polyoxyalkylene monoalkyl ether derivative, polymer of said derivative and dispersant comprising said polymer

机译:聚氧化烯单烷基醚,其制备方法,可聚合的聚氧化烯单烷基醚衍生物,所述衍生物的聚合物和包含所述聚合物的分散剂

摘要

A polymerizable polyoxyalkylene monoalkyl ether derivative prepared by using a polyoxyalklene monoalkyl ether which gives, in gel permeation chromatography, a chromatogram which satisfies a relation expressed by an equation: S1/S00.15, wherein S1 represents the area under a portion of the chromatogram from the start of elution to the earliest elution time when the intensity of the refractive index has a value of L/3, L representing the shortest distance between the greatest maximum point of the intensity of the refractive index and the base line and So represents the area under a portion of the chromatogram from the start of elution to an elution time when the intensity of the refractive index has the greatest maximum value; a process for producing the above ether comprising adjusting the content of water in a reactor, which is used in addition polymerization of alkylene oxides with addition to a monohydric alcohol, so as to satisfy an equation: Wi(CfCi)/V10, wherein the content of water in the reactor is obtained by placing a solvent having a content of water Ci (ppm) in an amount Wi (g) in the reactor having an inner volume V (ml), stirring the solvent to clean the reactor, removing the solvent from the reactor and obtaining a content of water Cf (ppm) in the removed solvent.
机译:通过使用聚氧烯基单烷基醚制备的可聚合的聚氧亚烷基单烷基醚衍生物,其在凝胶渗透色谱法中得到满足以下方程式表示的关系的色谱图:S 1 / S 0 0.15,其中S 1 代表从洗脱开始到最早洗脱时间(当折射率强度的值为L / 3时)色谱图中一部分的面积,L代表折射率强度的最大最大值与基线之间的最短距离,So表示从色谱图的开始到洗脱时间之间的部分色谱图,该区域是从折射率开始强度到最大值的洗脱时间;一种用于制备上述醚的方法,包括调节反应器中的水含量,该反应器用于与一元醇加成的环氧烷烃加成聚合反应,以满足方程式:Wi(CfCi)/ V10,其中通过在具有内部体积V(ml)的反应器中放置水含量为Wi(g),水含量为Ci(ppm)的溶剂,搅拌溶剂以清洁反应器,除去溶剂来获得反应器中的水从反应器中得到水,并在除去的溶剂中获得水Cf(ppm)的含量。

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