首页> 外国专利> Polyoxyalkylene monoalkyl ether, process for producing the same, polymerizable polyoxyalkylene monoalkyl ether derivative, polymer of said derivative and dispersant comprising said polymer

Polyoxyalkylene monoalkyl ether, process for producing the same, polymerizable polyoxyalkylene monoalkyl ether derivative, polymer of said derivative and dispersant comprising said polymer

机译:聚氧化烯单烷基醚,其制备方法,可聚合的聚氧化烯单烷基醚衍生物,所述衍生物的聚合物和包含所述聚合物的分散剂

摘要

A polymerizable polyoxyalkylene monoalkyl ether derivative prepared by using a polyoxyalklene monoalkyl ether which gives, in gel permeation chromatography, a chromatogram which satisfies a relation expressed by an equation: S1/S0≦0.15, wherein S1 represents the area under a portion of the chromatogram from the start of elution to the earliest elution time when the intensity of the refractive index has a value of L/3, L representing the shortest distance between the greatest maximum point of the intensity of the refractive index and the base line and S0 represents the area under a portion of the chromatogram from the start of elution to an elution time when the intensity of the refractive index has the greatest maximum value; a process for producing the above ether comprising adjusting the content of water in a reactor, which is used in addition polymerization of alkylene oxides with addition to a monohydric alcohol, so as to satisfy an equation: Wi×(Cf−Ci)/V≦10, wherein the content of water in the reactor is obtained by placing a solvent having a content of water Ci (ppm) in an amount Wi (g) in the reactor having an inner volume V (ml), stirring the solvent to clean the reactor, removing the solvent from the reactor and obtaining a content of water Cf (ppm) in the removed solvent.
机译:通过使用聚氧烯基单烷基醚制备的可聚合的聚氧亚烷基单烷基醚衍生物,其在凝胶渗透色谱法中得到满足以下方程式表示的关系的色谱图:S 1 / S 0 ≤0.15,其中S 1 代表从洗脱开始到最早洗脱时间(当折射率强度的值为L / 3时)色谱图中一部分的面积,L代表折射率强度的最大最大值与基线之间的最短距离与S 0 表示从洗脱开始到强度达到洗脱时间时色谱图中一部分的面积折射率的最大值最大。制备上述醚的方法,其包括调节反应器中的水含量,该反应器用于将环氧烷与一元醇加成加成聚合反应,以满足方程式:Wi×(Cf-Ci)/V≤参照图10,其中反应器中的水含量是通过将具有水量Ci(ppm)的溶剂Ci(ppm)的量Wi(g)放入具有内部体积V(ml)的反应器中,搅拌溶剂以清洁反应器中的水而获得的。反应器中,从反应器中除去溶剂,并在除去的溶剂中获得水Cf(ppm)的含量。

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