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Process to obtain nanometric powders of zirconium oxide with specific surface modification and its stable tetragonal structure.

机译:获得具有特定表面改性及其稳定的四方结构的氧化锆纳米粉末的方法。

摘要

Procedure for obtaining nanometric powders of zirconia with its specific surface modification and stable tetragonal structure.; The procedure is based on the initial formation of a sol by hydrolysis from a solution of zirconyl chloride and ammonia in an aqueous medium, which later evolves to a gel by polycondensation over time. Hydrogen peroxide is used as a modifying additive said gel structure with a beneficial effect on the final product to increase its molar ratio and an aging time of 30 minutes. With the process of the invention can reach obtained specific surfaces of the upper powders to 100 m {2} / g average particle sizes 10 to 100 nm.; Nanoscale powders obtained zirconia are of great interest in the preparation of catalysts, catalyst supports, solid electrolytes and as ceramic raw material.
机译:获得具有特定表面改性和稳定的四方结构的氧化锆纳米粉末的程序。该程序基于通过在水介质中从氧化锆氯化物和氨的溶液中水解而最初形成溶胶,然后随着时间的推移缩聚而演变成凝胶。过氧化氢用作所述凝胶结构的改性添加剂,对最终产物具有有益的作用,以增加其摩尔比和30分钟的老化时间。用本发明的方法可以得到上层粉末的比表面积达到100m {2} / g的平均粒径<10-100nm。氧化锆制得的纳米级粉末在制备催化剂,催化剂载体,固体电解质以及作为陶瓷原料方面引起了极大的兴趣。

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