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PROCESS FOR THE SYNTHESIS OF HEXANITROHEXAAZAISOWURTZITANE IN 2 STEPS FROM A PRIMARY AMINE

机译:一级胺分两步合成己二异氮杂异戊二烷的方法

摘要

P The present invention relates to a new process for the synthesis of hexanitrohexaazaisowurtzitane (HNIW), a compound useful as an energy charge in powders, propellants and explosives. This process comprises a first step for reacting an α, β derivative -dicarbonylated with a primary amine making it possible to form a hexasubstituted derivative of hexaazaisowurtzitane. The NHIW is then directly obtained, in a single reaction step, by nitration of the hexasubstituted derivative of hexaazaisowurtzitane. This process, in only 2 steps of a primary amine, is particularly simple and inexpensive. /P
机译:本发明涉及一种合成六硝基六氮杂异纤锌矿型结构烷烃(HNIW)的新方法,六硝基六氮杂异纤锌矿型结构烷烃可用作粉末,推进剂和炸药中的能量装料。该方法包括第一步,使α,β-二羰基衍生物与伯胺反应,从而可以形成六氮杂异纤锌矿型结构烷烃的六取代衍生物。然后在单个反应步骤中通过硝化六氮杂异纤锌矿型结构烷烃的六取代衍生物直接获得NHIW。仅伯胺的两个步骤的该方法特别简单且廉价。

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