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Surface modified colloidal abrasives, including stable bimetallic surface coated silica sols for chemical mechanical planarization
Surface modified colloidal abrasives, including stable bimetallic surface coated silica sols for chemical mechanical planarization
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机译:表面改性的胶体磨料,包括用于化学机械平面化的稳定的双金属表面涂覆的二氧化硅溶胶
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摘要
A composition and an associated method for chemical mechanical planarization (or other polishing) are described. The composition includes a surface-modified abrasive modified with at least one stabilizer and at least one catalyst differing from the at least one stabilizer. The composition can further include a medium containing the abrasive and an oxidizing agent (e.g., hydrogen peroxide), wherein the at least one catalyst is adapted to catalyze oxidation of a substrate by the oxidizing agent. Preferably, the abrasive is alumina, titania, zirconia, germania, silica, ceria and/or mixtures thereof, the stabilizer includes B, W and/or Al, and the catalyst is Cu, Fe, Mn, Ti, W and/or V. Both the stabilizer and the catalyst are immobilized on the abrasive surface. The method includes applying the composition to a substrate to be polished, such as substrates containing W, Cu and/or dielectrics.
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