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MACROMOLECULAR MATERIAL CONTAINING IONIC SUBSTITUENTS AND USE THEREOF IN ELECTROCHEMICAL SYSTEMS

机译:包含离子性取代基的大分子材料及其在电化学系统中的使用

摘要

The invention relates to a macromolecular material with ionic conduction. The material comprises a linear or branched or combed, possibly crosslinked, which carries ionic substituents; the ionic substituents are derived by reaction of the group Y, ionic monomers corresponding to the formula (I) M [Y- {O- (CHR) p- (CH2) q} nC (SO2R F) 2] m in which M is a cation of valence m; R F is a linear or branched perfluoroalkyl radical having 1 to 8 carbon atoms; R is a hydrogen atom or an alkyl radical having 1 to 4 carbon atoms; Y is an allyl, glycidyl, vinylbenzyl, acryloyl or methacryloyl group or a hydrogen atom; 0.ltoreq.n.ltoreq.40, 1.ltoreq.p + q.ltoreq.4; if n = 0, Y is an allyl or glycidyl or vinylbenzyl group. Use of the material as electrolyte in a rechargeable battery or as a binder in a composite electrode.
机译:本发明涉及具有离子传导性的高分子材料。该材料包括带有离子取代基的直链或支链或梳理的,可能是交联的。离子性取代基是通过基团Y与相应于式(I)M的离子性单体反应得到的[Y- {O-(CHR)p-(CH2)q} nC(SO2R F)2] m价阳离子m; R F为具有1至8个碳原子的直链或支链全氟烷基。 R是氢原子或具有1-4个碳原子的烷基; Y是烯丙基,缩水甘油基,乙烯基苄基,丙烯酰基或甲基丙烯酰基或氢原子; 0≤n≤40,1.≤p+q≤4;如果n = 0,则Y为烯丙基或缩水甘油基或乙烯基苄基。该材料在可再充电电池中用作电解质或在复合电极中用作粘合剂。

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