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Nylon MXD6 based biaxially stretched polyamide film of low permeability to gases and production method thereof

机译:透气性低的尼龙MXD6基双轴拉伸聚酰胺薄膜及其生产方法

摘要

The biaxially stretched film of the present invention comprises a polyamide resin composition (C) obtained by melt-kneading a smectite (B) with a polyamide (A) produced by the polycondensation of a diamine component containing 70 mol% or higher of m-xylylenediamine and a dicarboxylic acid component containing 70 mol% or higher of a C4-C20 α,ω-linear aliphatic dicarboxylic acid, or comprises at least one layer made of the polyamide resin composition (C). The polyamide resin composition (C) comprises the polyamide (A) in an amount of 80 to 99.9 parts by weight and the smectite (B) in an amount of 0.1 to 10 parts by weight. The layer made of the polyamide resin composition (C) has a relative peak intensity ratio of 60 or less. The relative peak intensity ratio is represented by the formula: B/A × 100, wherein A and B are intensities of the strongest peak and the next stronger peak appearing in a diffraction angle 2θ ranging from 15° to 25° of a CuKα X-ray diffraction pattern of the layer made of the polyamide resin composition (C), provided that A is the peak intensity of the peak at a lower angle and B is the peak intensity of the peak at a higher angle.
机译:本发明的双轴拉伸膜包含通过将蒙脱石(B)与由包含70摩尔%以上的间苯二甲撑二胺的二胺成分缩聚而得到的聚酰胺(A)熔融捏合而得到的聚酰胺树脂组合物(C)。含有70摩尔%以上的C 4 -C 20 α,ω-直链状脂肪族二羧酸的二羧酸成分,或至少由其构成的层聚酰胺树脂组合物(C)。聚酰胺树脂组合物(C)包含80至99.9重量份的聚酰胺(A)和0.1至10重量份的蒙脱石(B)。由聚酰胺树脂组合物(C)制成的层的相对峰强度比为60以下。相对峰强度比由下式表示:B / A×100,其中A和B是在CuKαX-的15°至25°的衍射角2θ中出现的最强峰和下一个更强峰的强度。聚酰胺树脂组合物(C)制成的层的X射线衍射图,条件是A是较小角度的峰的峰强度,B是较大角度的峰的峰强度。

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