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Cathode material for a high-temperature fuel cell (sofc) and a cathode that can be produced therefrom
Cathode material for a high-temperature fuel cell (sofc) and a cathode that can be produced therefrom
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机译:用于高温燃料电池(sofc)的阴极材料和可由其生产的阴极
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摘要
The invention relates to a cathode material, particularly for use in a high-temperature fuel cell, comprising substoichiometric Ln1-x-yMyFe1-zCzO3-δ, with 0.02≦×x≦0.05, 0.1≦y≦0.6, 0.1≦z≦0.3, 0≦δ≦0.25 and with Ln=lanthanides, M=strontium or calcium and C=cobalt or copper. By using a particular production method, in which this cathode material having a specified grain size is used, and in which a (Ce, Gd)O2-δ-intermediate layer is advantageously formed between the cathode and electrolyte, a cathode is obtained that, when used in a high-temperature fuel cell, can achieve a power greater than 1 W/cm2 already at 750° C. and a cell voltage of 0.7 V.
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机译:本发明涉及一种阴极材料,特别是用于高温燃料电池的阴极材料,包括亚化学计量的Ln 1-xy Sub> M y Sub> Fe 1-z Sub> C z Sub> O 3-δ Sub>,其中0.02≦xx≦0.05、0.1≦y≦0.6、0.1≦z≦0.3、0≦δ≦0.25 Ln =镧系元素,M =锶或钙,C =钴或铜。通过使用特定的生产方法,其中使用具有指定晶粒尺寸的该阴极材料,并且其中在阴极和阴极之间有利地形成(Ce,Gd)O 2-δ Sub>中间层。电解质,获得阴极,当将其用于高温燃料电池中时,可以在750℃和0.7 V的电池电压下实现大于1 W / cm 2 Sup>的功率。
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