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CATHODE MATERIAL FOR A HIGH-TEMPERATURE FUEL CELL(SOFC) AND A CATHODE THAT CAN BE PRODUCED THEREFROM
CATHODE MATERIAL FOR A HIGH-TEMPERATURE FUEL CELL(SOFC) AND A CATHODE THAT CAN BE PRODUCED THEREFROM
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机译:用于高温燃料电池(SOFC)的阴极材料和可以生产的阴极
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摘要
The invention relates to a cathode material, particularly for use in a high-temperature fuel cell, comprising substoichiometric Ln1-x-y MyFe1-zCzO3-delta, with 0.02 = x = 0.05, 0.1 = y = 0.6, 0.1 = z = 0.3, 0 = delta = 0.25 and with Ln = lanthanides, M = strontium or calcium and C = cobalt or copper. By using a particular production method, in which this cathode material having a specified grain size is used, and in which a (Ce, Gd)O2-delta-intermediate layer is advantageously formed between the cathode and electrolyte, a cathode is obtained that, when used in a high-temperature fuel cell, can achieve a power greater than 1 W/cm2 already at 750 °C and a cell voltage of 0.7 V.
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机译:本发明涉及一种特别用于高温燃料电池的阴极材料,其包括亚化学计量的Ln1-xyMyFe1-zCzO3-δ,其中0.02≤x≤0.05、0.1≤y≤0.6、0.1≤ z <= 0.3,0 <=δ<= 0.25,其中Ln =镧系元素,M =锶或钙,C =钴或铜。通过使用特定的制造方法,其中使用具有指定晶粒尺寸的该阴极材料,并且其中在阴极和电解质之间有利地形成(Ce,Gd)O 2-δ-中间层,获得了如下阴极:当用于高温燃料电池时,在750°C和0.7 V的电池电压下已经可以实现大于1 W / cm2的功率。
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