首页> 外国专利> FLEXIBLE POLYMER ELEMENT AS AN ENDURING AGENT IN PRE-PREGNATIONS.

FLEXIBLE POLYMER ELEMENT AS AN ENDURING AGENT IN PRE-PREGNATIONS.

机译:灵活的聚合物元素作为预制品中的必然代理。

摘要

A support structure comprising a flexible polymeric element in combination with reinforcing fibers for use in a curable composition with a resin matrix component in which the flexible polymeric element is in solid phase and is adapted to undergo a phase transition to the less partial to fluid phase, by dissolution during contact with the resin matrix component of the curable composition in which the polymer is soluble at a temperature that is lower than the temperature for the substantial onset of gelation and / or cure of the curable composition, characterized in that the transition from phase to fluid phase is by dissolving the soluble polymer in the resin matrix component, in which the matrix resin is curable and is selected from the group consisting of an epoxy resin, a resin addition-polymerization, especially a bis-maleimide resin, a formaldehyde condensate resin, especially a formaldehyde-phenol resin, a cyanate resin, an isocyanate resin, a phenolic resin and mixtures of two or more of the foregoing, and in which the flexible polymeric element comprises at least one polyaromatic sulfone comprising joined repeating units by ether, which optionally further comprise repeat units linked by thioether, the units consisting of - (PhAPh) n- and - (Ph) a- in which A = CO or SO2, Ph is phenylene, n = 1 a 2 and can be fractional, a = 1 to 4, preferably a = 1, 2 or 3 and, can be fractional and when it exceeds 1, said phenylenes are linearly linked through a single chemical bond or a divalent group other than CO- or -SO2- or are fused together directly or through a cyclic moiety, such as an alkyl acid group, an aromatic or cyclic (hetero) ketone, an amide, imide, imine; and in which the flexible polymeric element is in the form of a mono or multifiber, filament, tape, or mixtures or ligaments thereof.
机译:一种支撑结构,其包含柔性聚合物元件和增强纤维,用于与具有树脂基体组分的可固化组合物中的组合物,其中所述柔性聚合物元件为固相,并且适于经历向较少部分相至液相的相变,通过与可固化组合物的树脂基质组分接触期间的溶解而溶解,其中聚合物在低于可固化组合物基本上开始胶凝和/或固化的温度下可溶于其中的温度,其特征在于从相转变通过将可溶聚合物溶解在树脂基体组分中来形成液相,该基体树脂是可固化的,并且选自环氧树脂,树脂加聚反应,特别是双马来酰亚胺树脂,甲醛缩合物。树脂,尤其是甲醛-酚醛树脂,氰酸酯树脂,异氰酸酯树脂,酚醛树脂以及两种或多种的混合物且其中所述柔性聚合物元件包含至少一种聚芳族砜,所述聚芳族砜包含通过醚连接的重复单元,所述任选单元还包含通过硫醚连接的重复单元,所述单元由-(PhAPh)n-和-(Ph)组成a-其中A = CO或SO 2,Ph是亚苯基,n = 1a 2,并且可以是分数,a = 1-4,优选a = 1、2或3,并且可以是分数,并且当其超过1时,亚苯基通过单个化学键或除CO-或-SO2-以外的二价基团进行线性连接,或直接或通过环状部分(如烷基,芳族或环状(杂)酮,酰胺)稠合在一起,亚胺,亚胺;且其中柔性聚合物元件为单纤维或多纤维,细丝,带或其混合物或韧带的形式。

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