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A GAS TURBINE SINGLE PLANT MODIFYING METHOD, A CATALYST RE-USING METHOD AND A RE-PRODUCED CATALYST

机译:燃气轮机单厂改造方法,催化剂再利用方法和再生产催化剂

摘要

A method for economically modifying a gas turbine single plant into a combined cycle plant, a method for re-using a used high temperature denitration catalyst of the gas turbine single plant as an intermediate temperature denitration catalyst of other modified, existing or new plants and a re-produced catalyst are provided. The high temperature denitration catalyst of the gas turbine single plant contains TiO2, at least one of WO3 and MoO3 and V2O5 of 0.5 wt% or less, preferably 0.2 wt% or less or none of V2O5 and is optimized to be used in the temperature range up to maximum 450 to 600°C. The used high temperature denitration catalyst is immersed into V-containing water solution and dried and/or burned. An intermediate temperature denitration catalyst is re-produced containing V2O5 component of 0.5 wt% or more, preferably 1.0 wt% or more, and being optimized to be used in the temperature range of 250 to 450°C. This intermediate temperature denitration catalyst is re-used in the combined cycle plant after modified or other plants.
机译:一种将燃气轮机单厂经济地改造为联合循环电厂的方法,一种将燃气轮机单厂的用过的高温脱硝催化剂作为其他改造的,现有的或新的电厂的中温脱硝催化剂的再利用的方法以及一种提供了再生的催化剂。燃气轮机单设备的高温脱硝催化剂包含TiO 2,WO 3和MoO 3中的至少一种和V 2 O 5为0.5wt%以下,优选为0.2wt%以下或V 2 O 5不存在,并且被优化以在该温度范围内使用。最高温度450至600°C。将用过的高温脱硝催化剂浸入含V的水溶液中,进行干燥和/或燃烧。再生出中温脱硝催化剂,其包含0.5wt%以上,优选1.0wt%以上的V 2 O 5成分,并且将其优化以在250至450℃的温度范围内使用。该中温脱硝催化剂在改造后的工厂或其他工厂中在联合循环工厂中重复使用。

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