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PARTICULATE HYDROPHOBIC POLYMER, PRODUCTION PROCESS THEREFOR AND COLUMN FOR REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY

机译:颗粒状疏水性聚合物,制备方法及其逆相高效液相色谱柱

摘要

A particulate hydrophobic polymer produced by reacting (A) a particulate crosslinked polymer having a hydroxyl group with (B) a crosslinkable epoxy compound, hydrolyzing the epoxy bonds, and then reacting the obtained compound having a hydroxyl group with (C) an epoxy compound having from 6 to 40 carbon atoms in total, a production process therefor, a column for reversed-phase liquid chromatography, and an analysis method using the column. By using the particulate hydrophobic polymer of the present invention having a remarkably high acid/alkali resistance, a sharp chromatogram for polycyclic aromatic compounds is obtainable with the swelling and shrinkage of the particulate polymer itself reduced and without reducind the column efficiency among various solvents even when the eluent in the column is variously exchanged.
机译:通过使(A)具有羟基的颗粒状交联聚合物与(B)可交联的环氧化合物反应,水解环氧基,然后使所获得的具有羟基的化合物与(C)具有以下结构的环氧化合物反应而制备的颗粒状疏水性聚合物。总共6至40个碳原子,其制备方法,用于反相液相色谱的柱以及使用该柱的分析方法。通过使用本发明的具有显着高的耐酸/碱性能的粒状疏水性聚合物,可以获得多环芳族化合物的清晰的色谱图,同时粒状聚合物本身的溶胀和收缩降低,并且即使在多种溶剂之间,也不会降低柱效。色谱柱中的洗脱液可以进行各种交换。

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