首页> 外国专利> PROCESS FOR PREPARING LOW MOLECULAR WEIGHT OLEFIN POLYMERS, ORGANOMETALLIC TRANSITION METAL COMPOUNDS BISCYCLOPENTADIENYL LIGAND SYSTEMS AND CATALYST SYSTEMS

PROCESS FOR PREPARING LOW MOLECULAR WEIGHT OLEFIN POLYMERS, ORGANOMETALLIC TRANSITION METAL COMPOUNDS BISCYCLOPENTADIENYL LIGAND SYSTEMS AND CATALYST SYSTEMS

机译:制备低分子量烯烃聚合物,有机过渡金属化合物双环戊二烯基配体体系和催化剂体系的方法

摘要

The present invention relates to a process for preparing olefin polymers having a molar mass Mw of from 500 to 50 000 g/mol by polymerization or copolymerization of at least one olefin of the formula Ra-CH=CH-Rb, where Ra and Rb are identical or different and are each a hydrogen atom or a hydrocarbon radical having from 1 to 20 carbon atoms, or Ra and Rb together with the atoms connecting them can form a ring, at a temperature of from -60 to 200°C and a pressure of from 0.5 to 100 bar, in solution, in suspension or in the gas phase, in the presence of hydrogen and in the presence of a catalyst system comprising at least one organometallic transition metal compound and at least one cocatalyst, wherein the organometallic transition metal compound is a compound of the formula (I), specific organometallic transition metal compounds, biscyclopentadienyl ligand systems having such a specific substitution pattern, catalyst systems comprising at least one of the organometallic transition metal compounds of the invention and the use of the biscyclopentadienyl ligand systems of the invention for preparing organometallic transition metal compounds.
机译:本发明涉及一种通过使至少一种式Ra-CH = CH-Rb的烯烃聚合或共聚来制备摩尔质量Mw为500-50000g / mol的烯烃聚合物的方法,其中Ra和Rb为相同或不同,并且各自为氢原子或碳原子数为1至20的烃基,或者Ra和Rb与连接它们的原子一起可以在-60至200°C的温度和压力下形成环在溶液中,在悬浮液中或在气相中,在氢气的存在下以及在包含至少一种有机金属过渡金属化合物和至少一种助催化剂的催化剂体系的存在下,为0.5至100bar,其中所述有机金属过渡金属该化合物是式(I)的化合物,特定的有机金属过渡金属化合物,具有这种特定取代模式的双环戊二烯基配体体系,包含至少一种有机金属过渡金属的催化剂体系本发明的化合物和本发明的双环戊二烯基配体体系在制备有机金属过渡金属化合物中的用途。

著录项

  • 公开/公告号EP1848748A1

    专利类型

  • 公开/公告日2007-10-31

    原文格式PDF

  • 申请/专利权人 BASELL POLYOLEFINE GMBH;

    申请/专利号EP20050813813

  • 发明设计人 ELDER MICHAEL J.;

    申请日2005-11-18

  • 分类号C08F110/06;C08F4/642;C07F17/00;C07D333/78;

  • 国家 EP

  • 入库时间 2022-08-21 20:37:33

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