. Method involves interaction of fullerene-C60 c salsolidine in the presence of Cp2HfCl2 as a catalyst in toluene medium, at temperature 140-160C for 8-10 h. The yield of the end product is 62-83%. Invention provides the selective incorporation of one fragment in fullerene molecule to yield abovementioned compound of the formula (1) being synthesis of the latter is not described in literature. Synthesized compound can be used as chelating agent, sorbent and biologically active compound, and in creature of novel materials with desired electronic, magnetic and optical properties.;EFFECT: improved method of synthesis.;1 tbl, 9 ex"/>
METHOD FOR PREPARING 1-(6,7-DIMETHOXY-1,2,3,4-TETRAHYDROISOQUINOLINE-2-YLAMINO)-1,2-DIHYDRO60FULLERENE
FIELD: organic chemistry, chelating agents, chemical technology.;SUBSTANCE: invention relates to a method for synthesis of 1-(6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline-2-ylamino)-1,2-dihydro[60]fullerene of the formula (1) . Method involves interaction of fullerene-C60 c salsolidine in the presence of Cp2HfCl2 as a catalyst in toluene medium, at temperature 140-160C for 8-10 h. The yield of the end product is 62-83%. Invention provides the selective incorporation of one fragment in fullerene molecule to yield abovementioned compound of the formula (1) being synthesis of the latter is not described in literature. Synthesized compound can be used as chelating agent, sorbent and biologically active compound, and in creature of novel materials with desired electronic, magnetic and optical properties.;EFFECT: improved method of synthesis.;1 tbl, 9 ex
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机译：合成1-（6,7-二甲氧基-1,2,3,4-四氢异喹啉-2-基氨基）-1,2-的方法技术领域：有机化学，螯合剂，化学技术。式（1）的二氢[60]富勒烯。该方法涉及在甲苯介质中，温度为140- 160°C 8-10小时。最终产物的产率为62-83％。本发明提供了富勒烯分子中一个片段的选择性掺入以产生上述式（1）的化合物，因为后者的合成未在文献中描述。合成的化合物可用作螯合剂，吸附剂和生物活性化合物，并可用于具有所需电子，磁性和光学性质的新型材料中;效果：改进的合成方法。1tbl，9 ex
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