Improved harmonic marker formed from Fe-Ni-based soft magnetic alloy with nanocrystalline structure

摘要

The present invention discloses a process for enhancing the harmonic output of a marker comprising the steps of providing an amorphous alloy having a composition (Fe1-xNix)aMb(B1-ySiy)c wherein "x" ranges from about 0.2 to about 0.9, "y" ranges from 0 up to about 0.5, "a" is between about 60 and about 90 atomic %, "b" is between about 0.1 to about 10 atomic %, "c" is between about 0.1 to about 30 atomic percent, and M is at least one metal selected from the group consisting of Mo, Cr, Hf, Nb, Ta, Ti, V, W, and Zr, the amorphous alloy having at least two crystallization temperatures, a first crystallization temperature at which a nanocrystalline phase is formed, and a second crystallization temperature at which a second crystalline phase is formed; annealing the amorphous alloy at a temperature between the first and the second crystallization temperatures for a time sufficient to increase at least one harmonic characteristic of the element. Harmonic markers produced thereby are also disclosed.