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MODIFYING POLYETHYLENE MADE BY ZIEGLER OR SINGLE-SITE CATALYST WITH FREE RADICAL INITIATOR
MODIFYING POLYETHYLENE MADE BY ZIEGLER OR SINGLE-SITE CATALYST WITH FREE RADICAL INITIATOR
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机译:用自由基引发剂改性齐格勒或单站点催化剂制得的聚乙烯
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摘要
A method of modifying a polyethylene is disclosed. In the method ethylene or a mixture of ethylene and a C3-C10 α-olefin is polymerized in an organic solvent with a Ziegler or single-site catalyst to form an initial polyethylene solution. The initial polyethylene solution is then reacted with a free radical initiator to produce a modified polyethylene. The modified polymer has an enhanced melt elasticity and increased long chain branching index, and is essentially free of gel.
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