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STORAGE STABLE AZADIRACHTIN PESTICIDE FORMULATION

机译:储存稳定的叠氮灭鼠灵制剂

摘要

A storage stable, efficacious pesticide formulation is provided that is dilutable by the user and contains azadirachtin (AZA) and a pyrethrin or pyrethroid (PYR), and optionally an aprotic solvent and non-ionic, substantially water-free emulsifier. A sufficient amount of the PYR is provided to complex with the AZA A on opposite sides of the molecular structure thereof, thereby preventing rearrangement of the AZA A molecule in the presence of moisture that would result in hydrolysis and decomposition of AZA A. The AZA-PYR combination is sufficiently chemically stable such that less than 10% of the AZA A is decomposed when the formulation is subjected to an accelerated aging test for 30 days at 40°C in a sealed container. The molar ratio of PYR to AZA A is preferably within the range of 0.5/1 - 10.5/1, more preferably within the range of 1.5/1-7/1, and most preferably with the range of 3/1-6/1. A solvent, when provided, should be in the range of about 70% to about 90% by weight based on the weight of the formulation, and the emulsifier should be within the range of about 0% to about 20%.
机译:提供了一种贮存稳定,有效的农药制剂,其可由使用者稀释,并且包含印za素(AZA)和除虫菊酯或拟除虫菊酯(PYR),以及任选地非质子溶剂和非离子型,基本上无水的乳化剂。提供足够量的PYR以在其分子结构的相对侧与AZA A络合,从而防止在存在水分的情况下AZA A分子发生重排,这会导致AZA A水解和分解。 PYR组合具有足够的化学稳定性,因此在密封容器中于40°C对配方进行加速老化试验30天时,分解不到AZA A的10%。 PYR与AZA A的摩尔比优选在0.5 / 1至10.5 / 1的范围内,更优选在1.5 / 1-7 / 1的范围内,并且最优选在3 / 1-6 / 1的范围内。当提供溶剂时,基于制剂的重量,溶剂应在按重量计约70%至约90%的范围内,并且乳化剂应在约0%至约20%的范围内。

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