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NOVEL CADMIUM SELENIDE COMPLEXES, PROCESS FOR PREPARING OF THEREOF, AND CDSE NANOPARTICLE

机译:新型硒化镉络合物,其制备方法和CDSE纳米颗粒

摘要

A cadmium selenide complex is provided to produce pure cadmium selenide nanoparticles useful for manufacturing cadmium selenide quantum dots at low temperature. A cadmium selenide complex has a structure represented by the formula 1 of Y-Cd-Se(CH2)mO(CH2)nO-R', wherein Y is a halogen element or C1-7 linear or branched alkyl, R' is a C1-7 linear or branched alkyl, and m and n are, independently of each other, 1-7. A method for preparing a cadmium selenide complex represented by the formula 2 of X-Cd-Se(CH2)mO(CH2)nO-R' includes the step of reacting a cadmium(II) halide compound represented by the formula 3 of CdX2 with a selenide alkali metal salt compound represented by the formula 4 of MSe(CH2)mO(CH2)nOR'. In the formulae 2-4, X is a halogen element, R' is a C1-7 linear or branched alkyl, m and n are, independently of each other, 1-7, and M is Li, Na, or K.
机译:提供硒化镉络合物以产生纯的硒化镉纳米颗粒,其可用于在低温下制造硒化镉量子点。硒化镉配合物具有由Y-Cd-Se(CH2)mO(CH2)nO-R'的式1表示的结构,其中Y是卤素元素或C1-7直链或支链烷基,R'是C1 -7个直链或支链烷基,且m和n彼此独立地为1-7。 X-Cd-Se(CH2)mO(CH2)nO-R'的式2表示的硒化镉络合物的制备方法包括使CdX2的式3表示的卤化镉(II)化合物与CdX2反应的步骤。 MSe(CH 2)m O(CH 2)n OR’的式4表示的硒化物碱金属盐化合物。在式2-4中,X是卤素元素,R'是C1-7直链或支链烷基,m和n彼此独立地是1-7,并且M是Li,Na或K。

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