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Novel phosphonium-based ionic liquid and reaction solvent using the same

机译:新型phospho基离子液体和使用该离子液体的反应溶剂

摘要

Task: Provided is an ionic liquid of phosphinium salt whose viscosity is low and which does not affect the diffusion and convection of the reaction substrate whose reactivity with the reaction substrate is extremely low and whose water content is extremely low and which in this way as a solvent for various organic Synthesis reactions is usable. Means for Solving the Problem: An ionic liquid of quaternary phosphonium salt or a reaction solvent thereof, represented by the following formula (1): $ F1 [wherein R SUB 1 / SUB, R SUB 2 / SUB, R SUB 3 / SUB and R SUB 4 / SUB each represents a linear alkyl group having a carbon number of 1 to 6, a branched alkyl group, an alicyclic alkyl group or an alkoxyalkyl group represented by (CH SUB 2 / SUB) SUB n / SUB OR SUB 5 / SUB, (where n is an integer between 1 and 6 and R SUB 5 / SUB denotes a methyl group or an ethyl group) and at least one of R SUB 1 / SUB, R SUB 2 / SUB, R SUB 3 / SUB and R SUB 4 / SUB is an alkoxyalkyl group. R SUB 1 / SUB, R SUB 2 / SUB, R SUB 3 / SUB and R SUB 4 / SUB may be identical or different from each other, and R SUB 1 / SUB and R SUB 2 / SUB may be ring-shaped. X are anions.]
机译:任务:提供一种磷鎓盐的离子液体,其粘度低并且不会影响与反应底物的反应性极低且水含量极低且以这种方式作为反应形式的反应底物的扩散和对流。适用于各种有机合成反应的溶剂。解决问题的手段:季salt盐的离子液体或其反应溶剂,由下式(1)表示:$ F1 [其中R 1 ,R 2 ,R 3 和R 4 分别表示碳数为1至6的直链烷基,支链烷基,脂环族烷基或烷氧基烷基通过(CH 2 n 5 ,(其中n是1到6和R 5 之间的整数表示甲基或乙基)和R 1 ,R 2 ,R 3 和R 4 < / SUB>是烷氧基烷基。 R 1 ,R 2 ,R 3 和R 4 可以相同或不同,并且R 1 和R 2 可以是环形的。 X是阴离子。

著录项

  • 公开/公告号DE102008010534A1

    专利类型

  • 公开/公告日2008-10-16

    原文格式PDF

  • 申请/专利权人 NIPPON CHEMICAL INDUSTRIAL CO. LTD.;

    申请/专利号DE20081010534

  • 发明设计人

    申请日2008-02-22

  • 分类号C07F9/54;C07B49;C07C311/48;

  • 国家 DE

  • 入库时间 2022-08-21 19:49:09

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