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A photohardenable liquid silicone rubber composition for producing a master form

机译:用于生产母模的可光硬化液体硅橡胶组合物

摘要

PROBLEM TO BE SOLVED: To obtain the subject composition capable of giving a cured product bearing specific physical properties through photoirradiation, and thus capable of giving in a simple operation in a short time an impression aster block ena bling a photocurable liquid resin to be cured by rays through the wall surface of an aster block. ;SOLUTION: This liquid silicone rubber composition, which is capable of giving a cured product 20-60 in Shore A hardness and ≥10% in light transmittance when cured to 10mm thickness through photoirradiation, etc., irradiation with ultraviolet rays 200-500nm in wavelength, preferably comprises (A) 100 pts.wt. of an organopolysiloxane essentially comprising an organopolysiloxane of the formula (R is an aliphatic unsaturated bond-free monovalent hydrocarbon or alkoxy; R1 is an acryloyl-contg. group, vinyloxyalkyl, etc.; (a) and (b) are each a positive number satisfying the relationships: 1.9≤(a)2.4, 0.0003≤(b)≤0.1, and 1.9(a+b)≤2.4) bearing two or more photoreactive groups and having a viscosity of 100-1000,000cP at 25°C and (B) 0.01-5 pts.wt. of a photoinitiator.;COPYRIGHT: (C)1998,JPO
机译:解决的问题:获得能够通过光辐照得到具有特定物理性质的固化产物的主题组合物,并因此能够在短时间内以简单的操作给出压模紫胶块,该压模块使光固化性液态树脂能够通过固化而固化。射线穿过紫苑块的壁面。 ;解决方案:这种液态硅橡胶组合物,在通过200-500nm紫外线等光固化至10mm厚度时,能够提供肖氏A硬度为20-60的固化产物,透光率为10%以上。在波长上,优选包含(A)100pts.wt。基本上包含下式的有机聚硅氧烷的组成:(R为不含脂肪族不饱和键的单价烃或烷氧基; R Sup 1 =含丙烯酰基的基团,乙烯基氧基烷基等;(a)和(b)分别是满足以下关系的正数:1.9&le;(a)<2.4、0.0003&le;(b)&le; 0.1和1.9 <(a + b)&2.4;带有两个或多个光反应性基团和在25℃下粘度为100-1000,000cP,(B)为0.01-5pts.wt。光引发剂的制备。;版权:(C)1998,日本特许厅

著录项

  • 公开/公告号DE69717935T3

    专利类型

  • 公开/公告日2008-10-02

    原文格式PDF

  • 申请/专利权人

    申请/专利号DE1997617935T

  • 发明设计人

    申请日1997-09-24

  • 分类号C08L83/07;C08L83/04;

  • 国家 DE

  • 入库时间 2022-08-21 19:47:33

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